Fajan Rule: Greater is the polarization, greater is the covalent character. | Online Chemistry tutorial IIT, CBSE Chemistry, ICSE Chemistry, engineering and. This lesson will talk about polarization of ionic compounds and Fajans’ rules. Fajans’ rules discuss introduction of covalent character in ionic. Inorganic Chemistry/Chemical Bonding/Fajan’s Rule. From Wikibooks, open books for an open world. < Inorganic Chemistry | Chemical Bonding. Unreviewed.

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As the atoms in covalent compounds are held together by the shared electrons ,it is rigid rupe directional. Now, if we take a different example, for example AlF 3 Aluminium Fluoride. However, the remnants of Fajans’ Rules are found in Hard-Soft Acid-Base Theorywhich predicts bonding properties based on polarizability which is based on size and charge.

By using this site, you agree to the Terms of Use and Privacy Policy. Larger the charge on the cation, greater is its polarising power. Your email address will not be published.

They can be summarized in the following table: Two contrasting examples can illustrate the variation in effects. These compounds are molecular in nature and not ionic, their reactions are molecular and proceed at a much slower rate than those of ionic compounds.

If two cations have the same size and charge, then the one with 18 electrons in the outermost shell has greater polarising power than gajan other with 8 electrons in the outermost shell.

Views Read Edit View history. Thus, we get an ionic compound metal bonded to a nonmetal with slight covalent character.

Inorganic Chemistry/Chemical Bonding/Fajan’s Rule

The “size” of the charge in an ionic bond depends on the number of electrons transferred. The covalent character is found in compounds which have high polarizing cation and high polarizable anion.

Both a and b. Compounds are more likely to be covalent if: The fluorine’s electron cloud is definitely less shielded from the nuclear charge and will thus be less polarizable. In this case, the aluminium ion’s charge will “tug” on the electron cloud of iodine, drawing it closer to itself. This produces an ionic bond with covalent character.

They usually consists of molecules rather than ions. We see that a similar situation occurs, but instead of iodine we now have fluorine, a relatively small highly electronegative atom.

For help asking a good homework question, see: Fajans’ rules note the difference were formulated in by Kazimierz Fajans. Because if this electron cloud of anion is more diffused.

Fajan’s Rules | Chemical Bonding and Molecular Structure, Chemistry, Class 11

The large charge pulls on the electron cloud fwjan the iodines. Retrieved from ” https: The crystal structure of covalent compounds differ from that of ionic compounds. Covalent character of lithium halides fzjan in the order:. Comments It is very helpful thak u very much!!! Hence, atoms in a molecule can take up different directional arrangement and thus show structural and stereoisomerism.

Let us consider AlF 3this is an ionic bond which was also formed by transfer of electron. How do I ask homework questions on Chemistry Stack Exchange?

What Is Valence Bond Theory. Dajan page was last edited on 18 Novemberat Where as larger is the size of anion, more will be the polarization of anion. The greater is the polarisation produced, more is the neutralisation of the charges and hence the ionic character decreases or the covalent character increases.

Fajans’ rule states that a compound with low positive charge, large cation and small anion has ionic bond where as a compound with high positive charge, small cation and large anion are covalently bonded. By using our site, you acknowledge that you rrule read and understand our Cookie PolicyPrivacy Policyand our Terms of Service.

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Covalent compounds have low melting and boiling point because the molecules in covalent compounds are held together less rigidly.